[2,6-Bis(di-tert-butylphosphinomethyl)phenyl-κ3P,C1,P′](nitrato-κO)nickel(II)
نویسندگان
چکیده
منابع مشابه
Diaqua[μ-11,23-di-tert-butyl-3,7,15,19-tetraazatricyclo[19.3.1.19,13]tetracosa-1(25),2,6,9,11,13(26),14,19,21,23-dodecaene-25,26-diolato-κ4 N 3,N 7,O 25,O 26:κ4 N 15,N 19,O 25,O 26]dicopper(II) bis(perchlorate)
In the dinuclear title complex, [Cu(2)(C(30)H(38)N(4)O(2))(H(2)O)(2)](ClO(4))(2), the coordination cation has crystallographically imposed twofold rotational symmetry. The Cu(II) ion is five-coordinated by two N and two O atoms from the macrocylic ligand and one O atom from a water mol-ecule, forming a square-pyramidal N(2)O(3) geometry with the water mol-ecule in the apical position. The dista...
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The title compound, C(22)H(24)OSi or Ph(3)SiO(t)Bu, shows a distorted tetra-hedral coordination sphere around the Si atom. The C-O-Si angle is 135.97 (12)° and the O-Si distance is 1.6244 (13) Å. The mol-ecules are held together by weak inter-actions only. An H⋯H distance of 2.2924 (7) Å is found between aryl H atoms and is the shortest inter-molecular distance in the structure. With regard to ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808032376